Product ID:WASH & HORNET JET FREEZE 16 OZ
MSDS Date:04/29/1993
FSC:6840
NIIN:00N030982
MSDS Number: BXRGQ

WATERBURY CO INC

INDEPENDENCE, LA 70443
US

Emergency Phone: 800-424-9300 (CHEMTREC)

Info Phone: 203-597-1812

Preparer: J.C.A.

Cage: IO295

WATERBURY CO INC

640 INDEPENDENCE, LA 70443 US

Telephone: 203-597-1812;504-878-6751

Cage: IO295

PYRETHRUM; (PYRETHRINS)

CAS: 8003-34-7

RTECS: UR4200000

Fraction By Weight: 0.076%

OSHA PEL 5 MG/M3

ACGIH TLV: 5 MG/M3

EPA Report Quantity: 1 LB

DOT Report Quantity: 1 LB

TOLUENE, ALPHA-(2-(2-BUTOXETHOXY)ETHOXY)-4,5-

CAS: 51-03-6

RTECS: XS8050000

Fraction By Weight: 0.190%

OSHA PEL N/K

ACGIH TLV: N/K

CABARYL

CAS: 65-25-2

Fraction By Weight: 0.510%

OSHA PEL N/K

ACGIH TLV: N/K

ETHANE, 1,1,1-TRICHLORO-; (1,1,1-TRICHLOROETHANE) (SARA

CAS: 71-55-6

RTECS: KJ2975000

Fraction By Weight: 54%

OSHA PEL 350 PPM

ACGIH TLV: 350 PPM; 450 STEL

EPA Report Quantity: 1000 LBS

DOT Report Quantity: 1000 LBS

METHANE, DIMETHOXY-; (DIMETHOXY METHANE)

CAS: 109-87-5

RTECS: PA8750000

Fraction By Weight: 1%

OSHA PEL 1000 PPM

ACGIH TLV: 1000 PPM

SEC-BUTYL ALCOHOL; (SEC-BUTANOL) (SARA 313)

CAS: 78-92-2

RTECS: EO1750000

Fraction By Weight: 1%

OSHA PEL 150 PPM

ACGIH TLV: 100 PPM

ISOPARAFFINIC PETROLEUM DISTILLATE; (ISOPARAFFINIC

CAS: 68551-19-9

Fraction By Weight: 35-45%

OSHA PEL N/K

ACGIH TLV: N/K

2-PYRROLIDINONE, 1-METHYL-; (N-METHYL PYRROLIDONE)

CAS: 872-50-4

RTECS: UY5790000

Fraction By Weight: <5%

OSHA PEL N/K

ACGIH TLV: N/K

CARBON DIOXIDE

CAS: 124-38-9

RTECS: FF6400000

Fraction By Weight: <5%

OSHA PEL 5000 PPM

ACGIH TLV: 5000 PPM; 30000 STEL

PREPARED OR PROCESSED. DO NOT USE IN

RTECS: 9999999ZZ

PLASTIC, PAINTED OR VARNISHED SURFS OR DIRECTLY

RTECS: 9999999ZZ

ETC. TO REDUCE POSS STAINING ON PAINTED OR VINYL

RTECS: 9999999ZZ

15 MINUTES AFTER APPLICATION.

RTECS: 9999999ZZ

READ LABEL. STORE IN COOL DRY PLACE AWAY FROM

RTECS: 9999999ZZ

130F MAY CAUSE BURSTING. THIS PROD IS AUTHORIZED

RTECS: 9999999ZZ

GRADING PROGRAMS AS CATEGORY F2 SUBSTANCE. AEROSOL

RTECS: 9999999ZZ

LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER.
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:CHLOROCARBON MATLS HAVE PRDCED SENSIT
OF MYOCARDIUM TO EPINEPHRINE IN LAB ANIMALS & COULD HAVE SIMILAR
EFT IN HUMANS. ADRENOMIMETICS (EG, EPINEPHRINE) MAY BE
CONTRA-INDICATED EXCEPT FOR LIFE-SUSTAININ G USES IN HUMANS
ACUTELY/CHRONICALLY EXPOS TO CHLOROCARBONS . HDCH, NAUS, DIZZ,
INCOORDINATION, (EFTS OF OVEREXP)
Explanation of Carcinogenicity:NOT RELEVANT
Effects of Overexposure:HLTH HAZ: MUSC TWITCH, TREMORS, ABDOM CRAMPS,
DIARR, SWEAT, PINPOINT PUPILS, BLURRED VISION, SALIVATION, TEARING,
TIGHTNESS IN CHEST, CONVLS, CHOLINESTERASE INHIBITION. LAB STUDIES
HAVE SHOWN PETRO DI STILS, SIMILAR TO ONE IN THIS PROD, CANPRDCE
KIDNEY EFTS IN MALE RATS. SIGNIFICANCE OF THESE EFTS ARE UNLIKELY
(SUPDAT)
Medical Cond Aggravated by Exposure:ACUTE & CHRONIC LIVER DISEASE &
RHYTHM DISORDERS OF HEART. SKIN CNTCT MAY AGGRAVATE EXISTING DERM.
ALSO, ANY DISEASE, MEDICATION OR PRIOR EXPOS WHICH REDUCES NORM
CHOLINESTERASE ACTIVITY MAY (SUPDAT)

First Aid:INGEST: CALL MD OR POIS CTL CTR IMMED. GASTRIC LAVAGE IS
INDICATED IF MATL WAS TAKEN INTERNALLY. DO NOT INDUCE VOMIT; MAY
CAUSE ASPIR PNEUM HAZ. INHAL: REMOVE TO FRESH AIR. APPLY ARTF RESP
IF INDICATE D. SKIN: REMOVE CONTAMD CLTHG & WASH BEFORE REUSE. WASH
AFFECTED AREAS W/SOAP & WATER. GET MED ATTN IF IRRIT PERSISTS.
EYES: FLUSH W/PLENTY OF WATER FOR @ LEAST 15 MIN. GET MED ATTN IF
IRRIT PERSISTS.

Flash Point:NON FLAMMABLE
Extinguishing Media:CARBON DIOXIDE, DRY CHEMICAL, FOAM.
Fire Fighting Procedures:WEAR NIOSH/MSHA APPROVED PRESSURE DEMAND SCBA
AND FULL PROTECTIVE EQUIPMENT . KEEP CONTAINERS COOL TO AVOID
BURSTING.
Unusual Fire/Explosion Hazard:THERMAL DECOMPOSITION PRODUCTS MAY
INCLUDE HCL AND PHOSGENE . EXPOSURE TO TEMPERATURES ABOVE 130F MAY
CAUSE BURSTING.

Spill Release Procedures:IF CONTAINER IS RUPTURED OR BEGINS TO LEAK,
PLACE IN WELL-VENTILATED AREA FREE OF SPARKS & IGNIT SOURCES.
PESTICIDE THAT CANNOT BE USED ACCORDING TO LABEL INSTRUCTIONS MUST
BE DISPOSED OF ACCORDING TO ALL APPLICABLE LOCAL, STATE & FEDERAL
PROCEDURES.
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.

Handling and Storage Precautions:AVOID STORAGE NEAR FOOD/FEED. DO NOT
USE IN EDIBLE PROD AREAS OF FOOD PROCESSING PLANTS,
RESTAURANTS/OTHER AREAS WHERE FOOD IS COMMERCIALLY (ING 10)
Other Precautions:NO SMKNG IN AREA OF USE. DO NOT USE IN GEN VICIN OF
ARC WELDING, OPEN FLAMES OR HOT SURF. HEAT &/OR UV RADIA MAY CAUSE
FORM OF HCL &/OR PHOSGENE . IT IS VIOLATION OF FED LAW TO USE PROD
IN MANNE R INCONSISTENT W/ITS LABELING. (ING 14)

Respiratory Protection:NOT REQUIRED; AVOID BREATHING MIST. NIOSH/MSHA
APPROVED RESPIRATOR APPROPRIATE FOR EXPOSURE OF CONCERN .
Ventilation:LOCAL EXHAUST AS REQD TO KEEP AIRBORNE CONCS BELOW
ACCEPTABLE LEVELS. PROVIDE MECHANICAL (GEN) VENT ACCORDING TO
LABEL.
Protective Gloves:IMPERVIOUS GLOVES .
Eye Protection:ANSI APPRVD CHEM WORKERS GOGGS .
Other Protective Equipment:NONE SPECIFIED BY MANUFACTURER.
Work Hygienic Practices:FOLLOW LABEL INSTRUCTIONS.
Supplemental Safety and Health
FL PT METH: FLAME EXTENSION TEST. EFTS OF OVEREXP: DUE TO NUMBER OF
HUMAN STUDIES WHICH PRDCED NO EVID OF SUCH EFTS AT NORM OCCUP
LEVELS. CHRONIC OVEREXPS TO 1,1,1 TRICHLOROETHANE HAVE CAUSED LIVER
TO X EFTS IN EXPERIMENTAL ANIMALS. MED CNDTNS: INCR SUSCEPTIBLITY
TO TOX EFTS OF ACTIVE INGREDS.

Vapor Pres:2.069
Spec Gravity:1.12 (H*2O=1)
Solubility in Water:INSOLUBLE
Appearance and Odor:LARGE LIQUID STREAM REACHING 15 FEET.

Stability Indicator/Materials to Avoid:YES
STRONG ALKALINES, ACIDS, OXIDIZERS, ALUMINUM AND OTHER REACTIVE METALS.
Stability Condition to Avoid:OPEN FLAMES AND VERY HOT SURFACES CAN
CAUSE THERMAL DECOMPOSITION.
Hazardous Decomposition Products:HYDROGEN CHLORIE, SM AMTS OF PHOSGENE
& CHLORINE, CARBON DIOXIDE, CARBON MONOXIDE, NITROGEN OXIDE &
METHYL ISOCYANATE.

Waste Disposal Methods:DO NOT REUSE EMPTY CNTNR. REPLACE CAP, WRAP
EMPTY CNTNR IN NEWSPAPER & DISCARD IN TRASH. DO NOT PUNCTURE OR
INCIN. ANY REMAINING/COLLECTED LIQ FROM PUNCTURED CANS SHOULD BE
DISPOSED OF IN SAFE MANNER AT APPRVD FACILITY I/A/W LOCAL, STATE
&FED REGS.

Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.